Solvent Based Styrene-Butadiene-Styrene PSA Adhesive

Applicable Type Solvent borne Adhesives
Applicable Base Polymer Styrene block copolymers (SBC)
Applicable Industrial Sectors Industrial Assembly, Labels / Signs / Decals, Tapes

TYPICAL FORMULATION INGREDIENTS AND PROPERTIES

  Ingredient Parts by weight  
   SBS polymer, 30% styrene  100  
   Hydrogenated rosin ester  15  
   Coumarone-indene resin  70  
   ... and 3 more ingredients    
  Properties  
  T-peel strength on cotton duct, kN/m 10.7 (fabric failure)  

PROCESSING

APPLICABLE BASE POLYMER PROPERTIES

Styrene block copolymers (SBCs) offer cohesion, strength, and heat resistance for both pressures sensitive adhesives (PSAs) and non-pressure sensitive adhesives. The styrene phase forms a physically crosslinked network in the adhesive at room temperature. Of the SBCs, styrene butadiene styrene has the highest shear strength and moderately good peel strength.

Some of the advantages of SBCs in solvent borne adhesives and sealants are:
  • Polymers are directly soluble: no milling necessary
  • Solution times are shorter: greater productivity and efficiency
  • Solutions are more uniform: better control and reproducibility
  • Solution viscosity is lower: higher solids, level, lower solvent cost, greater thickness build
  • Solutions are stable: longer shelf life.

RESULTING PROPERTIES

A typical high strength solvent based styrene butadiene styrene pressure sensitive adhesive is provided above. It can be used for tapes and labels and general purpose applications. Open time, or the time between application of the adhesive coating and mating of the substrates, is an important parameter in PSA solvent-based adhesives. High melting styrene block copolymer resins may improve the temperature resistance of the adhesive, but their incorporation usually decreases the open time.

TIPS & TRICKS

 

Adhesives and Sealants Formulation Bulletin
SpecialChem4Adhesives Industry Letter
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