Fast Cure Epoxy-Acrylate Adhesives

Applicable Type Reactive Adhesives
Applicable Base Polymer Acrylics/ Acrylates, Epoxides (EP)
Applicable Industrial Sectors Automotive, Buildings & constructions, Electrical & Electronic Bonding, Industrial Assembly, Transportation (excl. Automotive)

TYPICAL FORMULATION INGREDIENTS AND PROPERTIES

  Phase Ingredient Parts by weight  
  Part A  Epoxy acrylate resin (EPON 8111, Resolution Performance Products)  Formulation 1: 100
Formulation: 2 100
 
  Part A  Fumed silica (Cab-O-Sil M5 Silica, Cabot Corp.)  Formulation 1: 5
Formulation 2: 5
 
  Part A  Ground quartz (Novacite 1250, Malvern Minerals Co.)  Formulation 1: 150
Formulation 2: 75
 
   ... and 4 more ingredients    
  Properties  
  Mix ratio by weight (Part A:Part B) Formulation 1: 11.5:1
Formulaton 2: 100:93
 
  Gel time at 25°C, 100 gm mass Formulation 1: 105 secs
Formulation 2: 225 secs
 
  Bond line gel time Formulation 1: 7 mins
Formulation 2: 45 mins
 
  Tensile shear strength, psi, on etched aluminum:  
 
  • 15 mins at 25°C
  • Formulation 1: 180  
     
  • 1 hrs at 25°C
  • Formulation 1: 340
    Formulation 2: 100
     
     
  • 24 hrs at 25°C
  • Formulation 1: 2600
    Formulation 2: 2800
     
     
  • 1 day at 25°C followed by 2 hrs at 100°C
  • Formulation 1: 2400
    Formulation 2: 4000
     

    PROCESSING

    APPLICABLE BASE POLYMER PROPERTIES

    Epoxy adhesives are generally more resistant to a wide variety of liquid environments than other structural adhesives. Acrylate resins are only one of several families that are compatible with epoxy chemistry. Acrylate monomers are extremely versatile building blocks that readily polymerize or copolymerize with a variety of other monomers. There are several types of epoxy acrylate hybrids that are possible.

    RESULTING PROPERTIES

    Epoxy polyacrylate adhesives find use where conventional epoxy adhesives are generally used but a fast cure is required. Conventional epoxy resins lack the ability to fully cure at temperature below 10°C. The epoxy polyacrylate resins react readily at low temperature and very rapidly at ambient temperatures.
    In addition to their fast cure rates at ambient temperatures and great reactivity at low temperatures, the epoxy polyacrylate adhesives provide other advantageous properties. These include:
    • Inherently low viscosity
    • Good physical strength and toughness
    • Superior wetting characteristics
    • Good adhesive properties
    • Good film forming properties.
    • Typical starting formulations for rapid setting, room temperature curing epoxy acrylate adhesive formulations are shown in the above table

    TIPS & TRICKS

     

    Adhesives and Sealants Formulation Bulletin
    SpecialChem4Adhesives Industry Letter
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