Polybutadiene Toughened RT Cure Epoxy Adhesives

Applicable Type Reactive Adhesives
Applicable Base Polymer Epoxides (EP)
Applicable Industrial Sectors Automotive, Buildings & constructions, Electrical & Electronic Bonding, Industrial Assembly, Tapes, Transportation (excl. Automotive)

TYPICAL FORMULATION INGREDIENTS AND PROPERTIES

  Phase Ingredient Parts by weight  
  Part A  Polybutadiene
Grade, Supplier Ricon 130MA20, Sartomer
 83.5  
  Part A  Maleic anhydride
Grade, Supplier Lindride 12, Lindau Corp.
 16.1  
  Part A  Catalyst
Grade, Supplier Byk A500, Byk Chemie
 0.2  
   ... and 3 more ingredients    

PROCESSING

APPLICABLE BASE POLYMER PROPERTIES

Epoxy adhesives are generally more resistant to a wide variety of liquid environments than other structural adhesives. However, they are generally considered to be very rigid systems, and as such they do not have exceptionally good impact or peel resistance unless modified with tougheners.

RESULTING PROPERTIES

The above table presents typical three component epoxy adhesive formulations using polybutadiene with maleic anhydride as a toughening agent. The material is mixed 2:1 Part A : Part B by weight and then the DAMA 1010 is mixed into the formulation.
This epoxy system is claimed to provide a hydrophobic backbone, low viscosity, softness and high tensile strength and adhesion. Typical cured properties are:
Hardness 75 Shore D
Tensile Strength 2650 psi
Lap Shear Strength 9350 psi
Tg 119°-127°C

This adhesive formulation can cure at either room temperature or elevated temperatures. Tensile shear strength and temperature resistance of these adhesives are relatively high. Peel strength is also high and does not decrease rapidly with lower temperatures. The durability of polybutadiene modified epoxies is satisfactory as measured by most long term moisture tests.

TIPS & TRICKS

 

Adhesives and Sealants Formulation Bulletin
SpecialChem4Adhesives Industry Letter
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